Rodine 2010 Corrosion Inhibitor for Boiler Chemical Cleaning

Boiler systems and pipelines associated with power plants and heating systems often face the problem of mineral scaling on the inner linings and transmission bends. This is mainly due to the residual hardness of the coolant water used. While treated water is essential, minute traces of partially soluble salts of calcium, magnesium, strontium, as well as due to silica and ferrous oxides. While scaling may lead to choking and rupture of transmission pipes, oxidation due to unregulated pH of boiler feed water can result in corrosion and pitting of metal. Thus various boiler scale removal chemicals are employed to clean and maintain optimum operation efficacy of boiler systems.

The two primary choices include Ammoniated EDTA and Ammoniated Citric acid for cleaning. They are both weak organic acids and remove mineral scales and oxides by oxidation and metal ion chelating. But as the case with all metal-acid processes, acids often corrode and cause damage to metal surfaces. And damaged/abraded inner linings of boiler pipes have a risk of exploding at high water temperature and pressure. Thus appropriate acid inhibitors are needed to limit the acid attack on base metal, therefore helping check economic loss and ensure safety.

Rodine 2010 is by far the most popular choice as corrosion inhibitor for chemicals used in boiler cleaning. It is a low toxicity, non-flammable, highly soluble low viscosity liquid metal loss inhibitor for use in tetra ammoniated EDTA and tetra ammoniated Citric acid cleaning solutions. Rodine 2010 not only minimizes ferrous metal loss during chemical cleaning of power plant boilers but also effectively prevents pitting and crevice corrosion of metal surface. Rodine 2010 has a maximum operating temperature of 350°F when used with EDTA and 200°F when used with Citric acid cleaning solution with an operational life of 24hours. Laboratory testing has confirmed that it is more soluble than other commercial inhibitors at elevated pH and advantageously permits post-oxidation and dissolution of metallic copper deposits at significantly higher rates than other commercial corrosion inhibitor chemicals.

ChemEqual serves as the largest online database of chemicals and their equivalents and Rodine Acid Inhibitors from various global suppliers and manufacturers can be found and enquired here.

Rodine 31A - Corrosion Inhibitor to limit acid attack on base metals

Formulated with an acidic blend of complex alkyl pyridines, 1, 3-diethyl thiourea, Rodine 31A serves as an aliphatic nitrogen corrosion inhibitor that provides protection to brass, steel and copper metals against the attack of sulfuric, phosphoric, sulfamic, formic acid, acetic oxalic acid, citric acid, bisulfate solution and mixtures thereof and conditionally for hydrochloric acid solutions. Rodine 31A Corrosion Inhibitor presents itself as a chloride free inhibitor. It has a maximum operating temperature of 180°F. It imparts excellent pickling and modifies the metal surface to help in the prevention of corrosion.

Acidic treatment is important in providing protection to the metals used in the industries against scaling and rusting. This acid treatment is mostly carried out variously to assist in the eradication of scale and rust but instead & often triggers abrasion of metals as they exhibit corrosive properties. This process not only influences the metal properties but also causes loss of base metals after acid solution pickling. Acidic Corrosion often causes gradual wearing off of material by acidic compounds.

This acidic corrosion is an electrochemical process which is directed by the diffusion of moisture, oxygen and availability of acidic pollutant on the metal surfaces. This brings about the requirement of acid inhibitors to aid in limiting the acid corrosion on base metal, therefore helping reduce the economical loss in several industrial sectors. The type and concentration of the corrosion inhibitor used is generally derived based on the type and properties of the metal to be protected and the conditions under which the metal is to be treated. Rodine 31A Corrosion Inhibitor is an acid inhibitor specifically to protect metals from corrosion by organic and mineral acids.

Features:

-Single product for multiple acids

-Helps in imparting excellent pickling

-Modifies metal surface to prevent corrosion

-Chloride free and is easily soluble with all acid concentrations

ChemEqual is the largest online directory of chemical suppliers, consisting of a vast database of manufacturers & suppliers that deal with trading of Rodine 31A Corrosion Inhibitor or other acid corrosion inhibitor products.

DOWCAL 200 Inhibited Propylene Glycol-based Heat Transfer Fluid - ChemEqual

Propylene glycol, also known as Propane-1,2-diol is used as a heat transfer fluid and antifreeze, particularly as a low corrosion non-toxic substitute to ethylene glycol based cooling systems. In aluminium based cooling systems like HVAC/R, propylene glycol has shown efficacy comparable to ethylene glycol.

Benefits of PG:

s  Low freezing point

s  The ability to decrease the freezing point of water

s  Burst protection

s  Low mammalian toxicity

s  Low flammability

s  Excellent heat transfer properties

s  A high boiling point, low vapor pressure

Water based fluids expand in volume when they freeze, causing rupturing of pipes and containment vessels. Ethylene glycol has severe toxicological and environmental implications making it unsuited for cases of human exposure. Water-PG mixtures in low temperature conditions do not create extra pressure on vessel walls and in case of leakage, they are not hazardous. This makes Propylene glycol the ideal active ingredient as heat transfer fluid in industrial systems.

DOWCAL 200 manufactured by DOW Chemicals is propylene glycol based heat transfer fluid antifreeze that has a wide range of application.  It has been formulated to operate at temperatures higher than what ordinary glycol fluids can. It has a low acute oral toxicity and includes a specially designed inhibitor package to prevent corrosion of common materials used in HVAC, Food beverage processing, solar power plants etc.

Applications:

·         Single fluid process heating and cooling

·         Closed-loop water based heating & air conditioning systems

·         Food and brewery industry

·         HVAC systems

·         Pharmaceuticals

·         Secondary cooling and heating

·         Freeze and Burst protection

·         Renewable energy systems

ChemEqual is a unique online chemical and equivalents database and B2B marketplace where Propylene Glycol based antifreeze like DOWCAL 200 and its equivalents can be easily searched and enquired here.

RODINE 92B Acid Inhibitor for Food Processing equipment cleaners - ChemEqual

Effective cleaning of equipment in the food processing industry is required to reduce chances for contamination of during preparation, processing, storage & serving. Cleaning prevents attraction of lower life forms like food pathogens, increases equipment life, boosts employee morale and efficiency and accounts for aesthetic considerations of consumers. The primary cleaning agent is water; free from disease producing organisms, toxic metal ions and objectionable taste & odor. But such quality of cleaning water is hard to achieve and chemicals are tailored to meet cleaner specifications based on water composition and operation type.

Acid Type Cleaners & Corrosion:

Acid cleaners are used in the food processing industry for milkstone removal and cleaning equipment like broth tanks, ingrediators etc. A wide choice of acid type cleaners for mineral scale removal exist today but organic acids and blends of organic acid type cleaners and chelating agents have found much popularity in recent times. This is because they are much less corrosive than mineral acids and alkaline cleaners. Citric acid and EDTA are frequently used for this purpose owing to a better pH regulation and less aggressive surface action.

Nevertheless, acid cleaning chemicals are corrosive to the base metal and are responsible for corrosion & pitting of surface. Inhibitors for Citric Acid descaling solution are usually applied at very low concentrations (1000-3000 ppm) to provide upto 99.8% corrosion inhibition during acid cleaning processes. Depending on the acid type used, specific corrosion inhibitors are designed to remove scales and deposits from equipment while minimizing base metal loss. They are of mostly polymeric origin and act by forming chelating structures, proving high efficiency as inhibitors in acid chemical cleaning operations.

RODINE 92B is a blend of semi-foaming corrosion inhibitors specifically formulated for preventing corrosion by Citric acid and EDTA based cleaners. It is highly efficient at protecting metal surfaces such as steel and copper alloys commonly associated with equipments in food processing and packaging industry. It has been shown to assist in surface cleaning and descaling actions by acid cleaners without any pitting or corrosion on metal surface.

With respect to the nature of industry where rodine acid inhibitors are used, toxicity issues for inhibitors is of prime concern & exposure to humans due to improper/inadequate rinsing is a possibility. Rodine 92B has been designed for such special applications and contains ingredients generally recognized safe to humans thus suitable for cleaning of food equipment.

Key product features are:

·         Modifies metal surface to prevent corrosion

·         Excellent wetting properties for better cleaning

·         Enhances cleaning efficiency

Rodine 92B is effective upto a temperature of 85°C/185°F and can be applied in all types of food processing, packaging & storage industries as inhibitor for acid cleaning systems.

ChemEqual is a online global chemical marketplace for Acid Inhibitors where Rodine type & its equivalent inhibitors can be found.

NALCOOL 2000 - Automobile Coolant Corrosion Inhibitor

Corrosion and scaling in automobile cooling systems is primarily by chemical reaction of oxidizing agents in the coolant on the metal components. The type and nature of materials present at heat exchanging surfaces, the temperature of the system, pH and type of corrosive elements present in the coolant determine the type of inhibitor package needed.

Conventional water based coolants constantly need additives in the form of mineral inhibitors such as phosphates, nitrites and borates for poplar heat exchange surface metals like aluminium, copper etc along with other parts made from cast iron & mild steel. Absence of suitable inhibitors can cause corrosion, metal cavitation, scaling and cause leaks by destruction on rubber gaskets and head caps. Liquid coolant additives serve ideally as easy to use blends that can be directly mixed with coolant water for easy and quick anti-corrosive action on coils, coolant pump and radiator fins.

Corrosion inhibitors are generally blends of chemicals added to the coolant water to reduce material loss and system damage due to oxidation. The prerequisite is a passivation agent to coat the metal surfaces preventing further corrosion followed by neutralization of oxidizing ions in the coolant thus reducing cavitation. Best corrosion inhibitors need to be fast acting and thermally stable so as to operate at high temperatures and high coolant flow rate. Nitrite, Borate, Silicate and Polyacrylate formulations seem to be the most popular as corrosion and rust inhibitors. This is due to the fact that they are able to remove most oxidizing agents in common coolants while passivating metal surfaces for a long lasting corrosion control. The only requirement is to keep a steady inhibitor concentration in the system.

NALCOOL 2000 manufactured by Nalco Company is a synergized inhibitor blend for metal passivation and sale suppression as a water soluble corrosion inhibitor. It has been designed for all common engine cooling systems and is ideal to protect ferrous metals, copper & its alloys, aluminium etc. as well as rubber gaskets and non-metallic components within the cooling system. NALCOOL 2000 is available in liquid form making it easy to use and apply, fully compatible with water and ethylene glycol based coolants. It does not contain chromates and has been tested internationally to maintain a high degree of heat transfer efficiency & long engine life.

Outstanding features of the product include:

s  Protection of all common cooling system metals

s  Cavitation protection

s  Minimized sludge and scale formation

s  Liquid, safe & easy to apply formulation

s  Compatible with wide range of coolants and dyes

s  Approved by all leading automobile engine manufacturers

NALCOOL 2000 is the perfect corrosion & scale inhibitor for coolants in small auxiliary diesel engines containing aluminium components.

ChemEqual is a vast online specialty chemical database and NALCOOL 2000 as well as equivalent compositions of coolant corrosion inhibitors can be found here from among a wide range of global suppliers.

Nalco PermaTreat PC-191 - RO Membrane Antiscalant

Reverse osmosis is a water purification technique developed in 1950’s by US government to remove dissolved solids in saline and brackish water. The principle involves application of waterline pressure over untreated water against a semipermeable membrane. The separated H₂O molecules pass through the membrane into a reservoir while contaminants remain on the other side. Over the years, RO has been extensively used for treating industrial feed water. While the primary method for demineralization is Ion exchange method, RO systems are adopted when large volumes of water need to be treated economically.

The life, efficiency & productivity of an RO Membrane water treatment system is greatly reduced due to a phenomenon called RO Membrane Scaling. During RO system operation, as the water moves through the membrane, the concentration of dissolved and suspended solids keep on increasing at the boundary layer. When the concentration exceeds saturation value, there occurs a tendency of deposition and crystallization on the membrane surface. Smaller depositions act as nuclei for more salt accumulation thus decreasing effectiveness of membranes and invoking frequent cleaning of the system. Scalants mostly include low soluble salts of calcium, barium, strontium as carbonates and sulfates and fine reactive silica crystals. Their low solubility makes them difficult to remove during cleanup processes.

Scaling can be minimized by pretreatment processes like ion exchange, chemical treatment like lime softening etc. but these incur higher costs.  In some cases, acidification is practiced to remove insoluble carbonates and sulfates and most commonly Hydrochloric Acid is used. Recently, the popular choice of RO scale treatment is the use of Antiscalants. Reverse Osmosis Antiscalants are specialized chemical formulations added to the untreated feed water to increase the solubility of sparingly soluble salts that cause scaling. They mostly comprise of acrylates and phosphonates that greatly inhibit carbonate and sulfate precipitation. Since they offer an online scale protection advantage, RO Antiscalants have become an essential part of operations involving reverse osmosis systems. Such systems avoid mineral scaling and need less frequent cleaning, show greater efficacy with high permeate quality, decreased water and energy consumption and longer operation life.

Nalco PermaTreat PC-191 is an RO Membrane Antiscalant manufactured by Nalco Company. It is a highly effective scale inhibitor engineered specifically for RO systems. It is suitable for treating brackish, highly saline and effluent feed water in RO filtration, Nanofiltration and Ultrafiltration systems. It is compatible with all types of RO membranes and can extend membrane life thus cutting down operating and maintenance costs.

Nalco PermaTreat PC-191’s characteristics can be ideally summarized as:

·         Effective against scales of calcium, strontium, barium salts of carbonate, sulfate and oxide origin

·         Zero scaling in system upto 2.6 LSI

·         Cleans by dispersing particulate fouling

·         Effective even at low feed water pH  upto 5.9

·         Can be fed directly or as diluted solution in system

·         Prevents formation of Iron scales

Nalco PermaTreat PC-191 helps resolve all scaling issues in RO Filtration systems and at all instances, the costs incurred are lower than would be for Ion exchange hardness removal methods. ChemEqual, the largest chemical marketplace gives the opportunity to buyer to compare and buy chemicals and equivalents.

Aquaculture Disinfectants: Types and Uses

Disinfection is a common disease management tool for aquaculture sector. It can be both a routine bio-security practice to prevent specific diseases or a routine sanitation process to reduce overall occurrence of diseases that may lower farm productivity. The nature and mode of disinfection greatly varies with the specific reason that leads to disinfection practices. The most commonly practiced approach is chemical treatment in specified doses and for sufficient retention periods to destroy pathogenic organisms that would otherwise access the water systems repetitively.

In aquaculture systems, the threat of cross contamination is prevalent between fauna in the same tank as well as between water holdings, both in fish and crustacean farming. In addition, use of disinfectants is not possible in open systems owing to environmental impacts of chemicals in natural waters and in case of seawater; there is risk of residual oxidant by-products due to chemical reactions with salts in water. Thus disinfectants can be applied safely and most conveniently only to hatcheries and incubation tanks.

Since most aquatic species are highly sensitive to toxic chemicals and the disposal of such waters threatens to contaminate natural water bodies, it is highly needed that a “safe” product be used for disinfection. The term “safe” implies to toxicity tolerance by farm as well as wild aquatic organisms. Thus only a few chemicals can truly adhere to the properties of ideal aquaculture disinfectants in real practice. Some disinfectants are effective against a large range of microorganisms: bacteria, viruses, fungi and parasites. In addition some chemicals are selective biocides to certain strains of exotic eutrophic microalgae. While some disinfectants can work on a short term before the microbes grow resistant to them. Thus the choice of disinfectant and methods of disinfection should be based on the spectrum and ease of application as well.

Requisites of an ideal Disinfectant are summarized herein:

-Should have a wide spectrum antimicrobial activity

-Should not be irritating to aquatic organisms or humans

-Should have minimal toxicity to non target organisms

-Should have high penetrability

-Should be active in presence of Pus and Necrotic Tissue

-Should be non-interfering with normal immunity of fishes

-Should be cost friendly

-Should be non corrosive and non staining

-Should be highly stable

-Should be biodegradable with nil/minimum bioaccumulation potential

Disinfectants can be classified based on their mode of activity as:

- Oxidizing Agents

-Reducing agents

-Detergents

Oxidizing Disinfectants can again be of two types:1

a. Those that oxidize without releasing oxygen, most common being Halogen bleachers and Potassium Permanganate and Peracetic Acid

b.  Those that oxidize by release of nascent oxygen i.e. Peroxides

They are mostly used to control phytoplankton, pathogens and bottom soil oxidants. Most oxidizing agents are irritant to skin and eyes in high concentrations and except for chlorine, most don’t have long bioaccumulation potential thus non contaminants to food.

Reducing agents consist of organic aldehydes like Formaldehyde and Glutaraldehyde that are popular general disinfectants used as germicide, fungicide or as preservatives in industries. Their main mode of action is by formation of covalent bonds and disruption of functional groups in cellular proteins. They are thus target specific and can be easily applied in selective removal of microbial contaminants. Aldehyde disinfectants are non-irritant, readily biodegradable and do not possess bioaccumulation risks.

Detergents or popularly referred to as Cationic detergents are Quaternary ammonium compounds (Benzalkonium Chloride) that are used I hatcheries to eradicate aquatic insect larvae and nematodes. They are active in disruption of cell membrane and destruction of cytoplasm and cell nuclear material. They are highly active against Gram negative bacteria. There are no known records of reactive products not degrading or chances of bioaccumulation in environment as of yet.

Irrespective of the mode of application and action most aquaculture disinfectants listed above seem to be highly effective in their respective treatment domain but choice of the same lies totally on the users end needs of disinfection and the type of pathogen to be controlled.

ChemEqual is a vast online chemical B2B marketplace and various grades and compositions of specific Aquaculture Disinfectants and Biocides can be searched here.

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